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In addition, testosterone administration has been associated with worsening of sleep-disordered breathing and obstructive sleep apnoea in susceptible individuals, thereby compounding cardiovascular strain and arrhythmic risk (85)

The example of GSH microspecies B and G (Table 2) shows that even minor changes in the sites of protonation can lead to differences in redox characteristics, this is all the more important in light of the complex, parallel protonation equilibria of these multibasic biomolecules: not only the protonation of the thiolate itself, its protonation fraction, and the concomitant redox behavior will be very sensitive to minor pH changes, but the protonation status of the adjacent basic moieties can influence the redox behavior by various inductive effects on the thiolate moiety

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Interestingly, adding exogenous ROS induced by TBHP led to PDCs with high expression of VRK2 susceptibility to APR-017 treatment (Fig