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Both phenolics are produced in the endoplasmic reticulum and transported to the vacuole (free form) and cell wall matrix (bound or insoluble form) (143, 144) where they attached (via covalent, ester, and ether bonds with a cell wall) with arabinoxylans, pectin, cellulose, structural proteins, and hemicellulose of the plant cell (143, 145)